Passing along a little info I got, sorry if it's a little redundant.
"There are several ways to get the VVC, but it has to come from the dealer who sold you the car. I couldn't get a hold of the general manager of my dealership, so I contacted the Service Manager. I gave them the following instructions, and they were able to download the VVC for me. Apparently, MBUSA has fielded many calls regarding how difficult it is to get the VVC because most managers have no clue. Again, only Sales Managers, GSM's (big boss), and Service Managers can do this. Go back to your dealer or service provider and send them the following instructions.
Login to NetStar, Click Sales or Service tab, Click VIP Tool link.
When new Daimler login page appears, must login with MBUSA for VIP Tool access credentials. Credentials different from NetStart ID.
Must enter customer's VIN and click search.
Click "Generate new master VVC".
Click "Print VVC info document".
Hopefully, that printout will be given to you. Good luck."